Per PH- Cure and Heal type spells do not work on Undead. This includes Lay on Hands (per PH), and by extension, any Cure or Heal potion or rubber.
Taking a page from previous editions- Inflict Wounds and Harm type spells will heal undead as if they were Cure or Heal spells. Tim's Lay on Hands will act as a Inflict Wounds so he can heal himself.
This also means that Cure and Heal type spells will damage the undead as if they were Inflict or Harm type spells.
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